153949-95-2Relevant academic research and scientific papers
4,8-Diphosphathiophenetriptycenes
Ishii, Akihiko,Yoshioka, Rie,Nakayama, Juzo,Hoshino, Masamatsu
, p. 8259 - 8262 (2007/10/02)
Unsubstituted and trimethyl-4,8-diphosphathiophenetriptycenes (4 and 3d) were synthesized by reduction of the corresponding phosphine oxides (8a and 8b) with trichlorosilane which were prepared by the reaction of trilithium salts, derived from tri-3-thienylphosphine oxides (7a and 7b), with P(OPh)3. The reaction of 3d with W(CO)5(THF) gave a 1:2 complex 12 in high yield.
