153977-33-4Relevant academic research and scientific papers
Stereoselective Total Synthesis of Polyether Ionophore Antibiotics, Isolasalocid A and Lasalocid A. Part 2. The Total Synthesis via Stereoselective Construction of the B Rings by Chelation-Controlled Cyclization under Thermodynamic Conditions
Horita, Kiyoshi,Noda, Ichio,Tanaka, Kazuhiro,Oikawa, Yuji,Yonemitsu, Osamu
, p. 5997 - 6018 (2007/10/02)
Stereoselective total synthesis of isolasalocid A (1) and lasalocid A (2) was achieved via construction of the tetrahydrofuran rings by chelation-controlled cyclization of the corresponding p-methoxyphenyl substituted allyl alcohols (6, 7) under thermodyn
Stereoselective synthesis of optically active 4-ethyl-3,5-dihydroxy-2- methylpentyl derivatives. A basic building block with three contiguous chiral centers of polyether antibiotics
Horita,Tanaka,Yonemitsu
, p. 2044 - 2046 (2007/10/02)
Optically active 4-ethyl-3,5-dihydroxy-2-methylpentyl derivatives, the iodide (4), phenyl sulfone (5), and phenyl sulfoxide (6), which are chiral synthons for an essential structural unit of polyether antibiotics, were stereoselectively synthesized starti
