154020-88-9Relevant academic research and scientific papers
Reactions of tertiary propargyl alcohols with sodium halides under oxidative conditions
Aborways, Marwa M.,Moran, Wesley J.
, p. 2127 - 2129 (2014/04/03)
The study of the reactions of tertiary propargyl alcohols with sodium halides under oxidative conditions is presented. With sodium iodide, α-iodoenones were formed, however, with sodium bromide or chloride the α-haloenones were only formed in low yields u
Hypoiodous acid initiated rearrangement of tertiary propargylic alcohols to α-iodoenones
Moran, Wesley J.,Rodríguez, Arantxa
, p. 8590 - 8592 (2013/01/15)
In the presence of an oxidant, sodium iodide is converted into hypoiodous acid which effects the rearrangement of tertiary propargylic alcohols to α-iodoenones in good yields.
Synthesis of haloenones and aryl or alkyl substituted enones or alkenes
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, (2008/06/13)
Alternative methods for synthesizing haloenones and haloakenes and their use as starting materials for synthesis of substituted or unsubstituted alkyl and aryl substituted enones and alkenes, including tamoxifen and tamoxifen analogs, using such haloenone
Conversions of phenylalkynylcyclopentanols to α-iodoenones
Bovonsombat, Pakorn,Mc Nelis, Edward
, p. 8205 - 8208 (2007/10/02)
N-Iodosuccinimide and catalytic amounts of Koser's reagent react with phenylalkynyleyclopentanols to afford α-iodoenones. No ring expansions occur.
