154030-95-2Relevant academic research and scientific papers
Unprecedented silicon(ii)→calcium complexes with N-heterocyclic silylenes
Blom, Burgert,Klatt, Günter,Gallego, Daniel,Tan, Gengwen,Driess, Matthias
, p. 639 - 644 (2014)
The first N-heterocyclic silylene (NHSi) complexes of any s-block element to date are reported for calcium: [(η5-C5Me5)2Ca←:Si(O-C6H4-2-tBu){(NtBu)2CPh}] (6
A stable silylene in a reactive environment: Synthesis, reactivity, and silicon extrusion chemistry of a coordinatively unsaturated ruthenium silylene complex containing chloride and η3-P-C-P ligands
Amoroso, Dino,Haaf, Michael,Yap, Glenn P.A.,West, Robert,Fogg, Deryn E.
, p. 534 - 540 (2008/10/08)
Reaction of [(dcypb)ClRu(μ-Cl)3Ru(dcypb)(N2)] (1) with 4 equiv of the stable silylene 1,3-di-tert-butyl-l,3,2-diazasilol-2-ylidene (SiL2N) yields coordinatively unsaturated RuCl(η3-dcypb)(SiL2/s
