154084-90-9

Upstream product

• 472-63-9 2-(2,6,6-trimethyl-cyclohex-2-enyl)-ethanol 

Downstream Products

• 154084-91-0 1,5-Dimethoxy-6-[2-(2,6,6-trimethyl-cyclohex-2-enyl)-ethyl]-cyclohexa-1,4-diene 
• 154084-93-2 2-(2-(2,6,6-trimethyl-2-cyclohexenyl)ethyl)-3-(trifluoromethansulfonyl)oxy-cyclohexenone 
• 154084-92-1 2-(2-(2,6,6-trimethyl-2-cyclohexenyl)ethyl)-1,3-cyclohexadione 
• 52567-91-6 (1S*,6R*)-1,7,7-Trimethyl-2-oxabicyclo<4.4.0>decan-3-one 
• 145631-62-5 5-((1R,2S)-2-Hydroxy-2,6,6-trimethyl-cyclohexyl)-3-methylene-pentan-2-one 
• 52567-87-0 (1R*,2S*)-2-(3-Hydroxypropyl)-1,3,3-trimethyl-1-cyclohexanol 
• 178616-48-3 (+/-)-Ethyl 2-<2-(2,6,6-trimethyl-2-cyclohexen-1-yl)ethyl>-3-oxobutanoate 

Relevant academic research and scientific papers

Application of intramolecular Heck reactions to the preparation of steroid and terpene intermediates having cis A-B ring fusions. Model studies for the total synthesis of complex cardenolides

The cis-fused tricyclic dienone 13 is the major product formed from intramolecular Heck cyclization of the dienyl triflate 12 (Scheme I). Similarly, the cis-hexahydrophenanthridine 22 is formed in good yield from Heck cyclization of the aryl triflate 21.

Synthesis of mono- and sesquiterpenoids, XXV: Synthesis of (6R*,7R*)-7-hydroxy-6,11-cyclofarnes-3(15)-en-2-one, the racemate of the antibacterial sesquiterpene from premna oligotricha, and its (6R*,7R*) isomer

The structure of the antibacterial sesquiterpene from Premna oligotricha was shown to be not 1 but 2 (relative stereochemistry) by the unambiguous synthesis of both (±)-1 and (±)-2. VCH Verlagsgesellschaft mbH, 1996.