154084-98-7

Basic information

• Product Name: 2-Benzyloxymethyl-1-vinyl-cyclohex-2-enol
• Synonyms: 2-Benzyloxymethyl-1-vinyl-cyclohex-2-enol
• CAS NO: 154084-98-7
• Molecular Weight: 244.334
• Mol File: 154084-98-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Benzyloxymethyl-1-vinyl-cyclohex-2-enol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Benzyloxymethyl-1-vinyl-cyclohex-2-enol(154084-98-7)
• EPA Substance Registry System: 2-Benzyloxymethyl-1-vinyl-cyclohex-2-enol(154084-98-7)

Safety Data

• Hazardous Substances Data: 154084-98-7(Hazardous Substances Data)

Upstream product

• 70156-98-8 6-bromo-1,4-dioxaspiro[4,5]dec-6-ene 
• 917-57-7 vinyllithium 
• 154084-96-5 2-[(benzyloxy)methyl]cyclohex-2-en-1-one 
• 3587-60-8 Benzyloxymethyl chloride 

Downstream Products

• 154085-00-4 2-{2-[2-Benzyloxymethyl-1-(tert-butyl-dimethyl-silanyloxy)-cyclohex-2-enyl]-ethyl}-phenol 
• 154085-01-5 2-<(2-benzyloxymethyl)-1-(tert-butyldimethylsiloxy-2-cyclohexen-1-yl)ethyl>phenyl trifluoromethanesulfonate 
• 154084-97-6 2-(benzyloxymethyl)-1-tert-butyldimethylsiloxy-1-ethenyl-2-cyclohexene 

Relevant articles and documents

Application of intramolecular Heck reactions to the preparation of steroid and terpene intermediates having cis A-B ring fusions. Model studies for the total synthesis of complex cardenolides

The cis-fused tricyclic dienone 13 is the major product formed from intramolecular Heck cyclization of the dienyl triflate 12 (Scheme I). Similarly, the cis-hexahydrophenanthridine 22 is formed in good yield from Heck cyclization of the aryl triflate 21.