15409-83-3Relevant academic research and scientific papers
Novel robust benzimidazolylidene palladium complexes: Synthesis, structure, and catalytic applications in amination of chloroarenes
Fang, Weiwei,Jiang, Jian,Xu, Yong,Zhou, Juefei,Tu, Tao
, p. 673 - 679 (2013/07/27)
A series of novel pyridine stabilized PdeNHC complexes were developed, which revealed high activities and broad substrates tolerance in the amination of various (hetero)-aryl chlorides. Besides various secondary amines, a wide range of primary anilines and aliphatic amines were also well tolerated. The results highlight us a new strategy to increase catalyst activity in the future catalyst design by alternating the σ-donor property and flexibility of NHC ligands.
