1541-14-6

Basic information

• Product Name: 1,3,5-Cycloheptatriene, 1-phenyl-
• CAS NO: 1541-14-6
• Molecular Formula: C13H12
• Molecular Weight: 168.238
• Mol File: 1541-14-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,3,5-Cycloheptatriene, 1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-Cycloheptatriene, 1-phenyl-(1541-14-6)
• EPA Substance Registry System: 1,3,5-Cycloheptatriene, 1-phenyl-(1541-14-6)

Safety Data

• Hazardous Substances Data: 1541-14-6(Hazardous Substances Data)

Usage

Structure

Cyclic hydrocarbon with a seven-membered ring and a phenyl group attached to one of the carbon atoms

Physical state

Colorless liquid at room temperature

Usage

Commonly used in chemical research and synthesis

Reactivity

Highly reactive due to the presence of unsaturated carbon-carbon bonds in its ring structure

Properties

Aromatic

Applications

Valuable building block in the production of various organic compounds and materials

Safety

Handle with caution and follow proper safety protocols in a laboratory setting

Upstream product

• 1018955-90-2 6-phenylbicyclo[3.2.0]hept-2-en-6-ol 
• 1714-39-2 7-ethoxy-1,3,5-cycloheptatriene 
• 544-25-2 Cyclohepta-1,3,5-triene 
• 71-43-2 benzene 
• 1541-11-3 7-phenylcycloheptatriene 

Downstream Products

• 1203-68-5 2-Phenylbenzaldehyde 
• 906436-33-7 3-([1,1'-biphenyl]-4-ylmethylene)pentane-2,4-dione 
• 1204-60-0 biphenyl-3-carbaldehyde 
• 3218-36-8 4-Phenylbenzaldehyde 

Relevant articles and documents

An oxidative rearrangement of 6-phenylbicyclo[3.2.0]heptan-6-ol to 1,1′-biphenyl-carbaldehydes: A mechanistic study

Acid-catalyzed rearrangement of 6-phenylbicyclo[3.2.0]heptan-6-ol gave 1,1′-biphenyl and 1,1′-biphenyl-carbaldehydes in small amounts as well as the expected rearrangement products. A detailed study of the reaction mechanism revealed that the conversion occurs via an oxidative process through the consecutive formation of cycloheptadienes, cycloheptatrienes, and 1,1′-biphenyls. The acid-catalyzed rearrangement of 6-phenylbicyclo[3.2.0] hept-2-en-6-ols gave 1- and 2-phenylcycloheptatrienes directly, from which 1,1′-biphenyl and 1,1′-biphenyl-carbaldehydes were obtained by oxidation.

Direct Proton-Transfer Reaction via a Transient Hydrogen Bond Bridged Allyl Anion System on the Models of Cycloheptatrienes and Propene

The base-catalyzed intramolecular proton transfer in cycloheptatriene derivatives and propene has been investigated both theoretically and experimentally.A direct 1,3-intramolecular proton shift was observed in cycloheptatriene derivatives, the shift proc