15413-06-6Relevant articles and documents
-bis Complexes of the Group 6B Elements: Synthesis and Spectroscopic Study
Oezer, Zahide,Oezkar, Saim,Pamuk, H. Oe.
, p. 37 - 43 (2007/10/02)
-bis complexes (CO)5MR2P(CH2)nPR2M(CO)5, (M: Cr, Mo, W; n: 1,2,3; R: CH3, C2H5, C6H5) were synthesized from the reaction of M(CO)5(CH3CN) with the appropriate ligand and characterized by means of IR and NMR (1H, 13C, 31P) spectroscopy.Spectral data indicate that the complexes contain two identical M(CO)5 moieties linked to each other by the R2P(CH2)nPR2 ligand.Each metal atom has a pseudo-octahedral arrangement of the five CO ligands and one phosphorus atom.Keywords: Chromium, Molybdenum, Tungsten, Dinuclear Complexes, Diphosphine