1542214-99-2Relevant academic research and scientific papers
Activation of aryl halides at gold(i): Practical synthesis of (P,C) cyclometalated gold(III) complexes
Guenther, Johannes,Mallet-Ladeira, Sonia,Estevez, Laura,Miqueu, Karinne,Amgoune, Abderrahmane,Bourissou, Didier
supporting information, p. 1778 - 1781 (2014/03/21)
Taking advantage of phosphine chelation, direct evidence for oxidative addition of Csp2-X bonds (X = I, Br) to a single gold atom is reported. NMR studies and DFT calculations provide insight into this unprecedented transformation, which gives straightforward access to stable (P,C) cyclometalated gold(III) complexes.
