154243-37-5Relevant academic research and scientific papers
Application of the ring-closing metathesis to the formation of 2-aryl-1H-pyrrole-3-carboxylates as building blocks for biologically active compounds
Grychowska, Katarzyna,Kubica, Bart?omiej,Drop, Marcin,Colacino, Evelina,Bantreil, Xavier,Paw?owski, Maciej,Martinez, Jean,Subra, Gilles,Zajdel, Pawe?,Lamaty, Frédéric
, p. 7462 - 7469 (2016)
Ring-closing metathesis (RCM) is a powerful tool for the preparation of cyclic organic compounds. Yet, one of the major limitations of this method is the difficulty to prepare large quantities of target molecules. Herein we describe a comprehensive study
Highly Diastereoselective Coupling Reactions between Chiral Benzaldehyde Tricarbonylchromium Complexes and Activated Double Bonds
Kuendig, E. Peter,Xu, Long He,Romanens, Patrick,Bernardinelli, Gerald
, p. 7049 - 7052 (2007/10/02)
The amine catalyzed coupling reaction of acrylic derivatives with benzaldehydes (Baylis-Hillman reaction) is more efficient when the arene is complexed to the electrophilic Cr(CO)3 group.Reactions with planar chiral o-substituted benzaldehyde complexes ar
