1542558-97-3Relevant academic research and scientific papers
Synthesis, crystal structures, and magnetic properties of three iron(II) complexes with 3-(p -bromophenyl)-4-phenyl-5-(2-pyridyl)-1,2,4-triazole
He, Xin,Cao, Dong-Yong,Jiang, Jing-Jing,Shen, Xuan,Zhu, Dun-Ru
, p. 227 - 235 (2014)
Three iron(II) complexes with 3-(p-bromophenyl)-4-phenyl-5-(2-pyridyl)-1,2, 4-triazole (L), trans-[FeL2(NCS)2] (1), trans-[FeL 2(NCS)2]·2MeOH (1·2MeOH), and trans-[FeL2(NCSe)2] (2), have been synthesized and characterized by elemental analysis, FT-IR, ESI-MS, and single crystal X-ray crystallography. Crystallographic studies reveal that all the complexes contain a distorted octahedral [FeN6] core with two trans NCS(Se)- ions. Each L adopts a chelating bidentate coordination via one N of pyridyl and one N of triazole. Magnetic susceptibility measurement indicated that both 1 and 1·2MeOH are in a high-spin state from 2 to 300 K. 2014
