1542799-82-5Relevant academic research and scientific papers
Formation of novel T-shaped NNN ligands via rare-earth metal-mediated Si-H activation
Bubrin, Denis,Niemeyer, Mark
supporting information, p. 1269 - 1271 (2014/03/21)
Reactions of silylamides [Ln{N(SiHMe2)2} 3(thf)2] with sterically crowded terphenylamine DmpNH 2 (Dmp = 2,6-Mes2C6H3 with Mes = 2,4,6-Me3C6H2) afforded via a template reaction the formation of a new tridentate ligand, and derived complexes of composition [LnN{SiMe2N(Dmp)}2] (Ln = Ce, Pr) were obtained. Usage of the even more bulky amine ArNH2 (Ar* = 2,6-Trip 2C6H3 with Trip = 2,4,6-iPr3C 6H2) yielded the free protonated ligand NH{SiMe 2NH(Ar)}2.
