1542886-05-4Relevant academic research and scientific papers
Ruthenium catalyzed desymmetrization of diazabicyclic olefins to access heteroaryl substituted cyclopentenes through C-H activation of phenylazoles
Aparna,Prabha,Prakash, Praveen,Jijy,Luxmi Varma,Radhakrishnan
, p. 865 - 868 (2015)
The first ruthenium catalyzed redox-neutral C-H activation strategy for the ring-opening of diazabicyclic olefins via C-H bond cleavage of phenyl azoles is reported. The developed method offers a novel route to functionalized cyclopentenes by employing less-expensive ruthenium catalyst and readily accessible biologically significant heteroarenes. The present protocol is a merger of the C-H activation of phenyl substituted heteroaromatics and subsequent β-nitrogen elimination of diazabicyclic olefins.
Rhodium(III)-Catalyzed C-H activation of phenylazoles toward C-N bond cleavage of diazabicyclic olefins: A facile access to mono- and biscycloapentenyl-functionalized aza-heteroaromatics
Prakash, Praveen,Aparna,Jijy,Santhini,Varughese, Sunil,Radhakrishnan
supporting information, p. 275 - 279 (2014/02/14)
A [RhCl2Cp]2-catalyzed stereoselective C-N bond cleavage of diazabicyclic olefins via C-H activation of phenylazoles in the presence of an acetate source is described. The developed method provides an easy access to biologically significant mono- and biscyclopentenyl- and alkylidenecyclopentenyl-functionalized aza heteroaromatics. Georg Thieme Verlag Stuttgart, New York.
Ruthenium catalyzed desymmetrization of diazabicyclic olefins to access heteroaryl substituted cyclopentenes through C-H activation of phenylazoles
Aparna,Prabha,Prakash, Praveen,Jijy,Luxmi Varma,Radhakrishnan
, p. 865 - 868 (2014/02/14)
The first ruthenium catalyzed redox-neutral C-H activation strategy for the ring-opening of diazabicyclic olefins via C-H bond cleavage of phenyl azoles is reported. The developed method offers a novel route to functionalized cyclopentenes by employing less-expensive ruthenium catalyst and readily accessible biologically significant heteroarenes. The present protocol is a merger of the C-H activation of phenyl substituted heteroaromatics and subsequent β-nitrogen elimination of diazabicyclic olefins.
