1542929-38-3Relevant academic research and scientific papers
Different ZnII cation coordination geometries in di-μ-acetato-bis{2-chloro-6-[(pyridine-2-ylmethylimino)methyl]phenol} dizinc(II) chloroform monosolvate
Kim, Young-Inn,Lee, Jin Young,Song, Young-Kwang,Kang, Sung Kwon
, p. 1348 - 1350 (2013)
In the title compound, di-μ-acetato-κ2 O:O;κ2 O:O′-bis[(6-chloro-2-{(E)-[(pyridin-2-yl) methylimino]methyl}phenolato-κ3 N,N′,O)zinc(II)], [Zn2(C13H10ClN2O)2(C 2H3O2)2]·CHCl3, the ZnII cation adopts a five-coordinate geometry and is coordinated by two N atoms and one O atom of a tridentate 6-chloro-2-{(E)-[(pyridin-2-yl) methylimino]methyl}phenolate ligand and two O atoms of two bridging acetate groups, but their coordination geometries differ. One ZnII cation adopts a distorted trigonal bipyramidal geometry and the other a square-pyramidal geometry. The two acetate ligands bridge two ZnII cations with mono-and bidentate coordination modes. The title compound exhibits a strong emission at 460 nm upon excitation at 325 nm with a quantum yield of 23.1%.
