154313-15-2Relevant academic research and scientific papers
REACTION OF α-HALOHYDRAZONES WITH PRIMARY THIOAMIDES
Benincori, Tiziana,Brenna, Elisabetta,Sannicolo, Franco,Trimarco, Licia,Pilati, Tullio
, p. 531 - 538 (2007/10/02)
The reaction of several α-chloroarylhydrazones, 2, with thioacetamide or a thioacetamide-thiobenzamide mixture in refluxing toluene affords 5-substituted-2,3-dihydro-3-aryl-2-(thioacyl)methylene-1,3,4-thiadiazoles, 5.Two 1,6-dithia-3,4-diazaspironona-2,8-diene derivatives (6) and a 1,3,4-thiadiazepine derivative (7) obtained as by-products are the first examples of these heterocyclic systems.
