154459-11-7

Upstream product

• 40217-17-2 (R)-4-(phenylmethyl)-2-oxazolidinone 
• 19810-31-2 Benzyloxyacetyl chloride 
• 123-73-9 trans-Crotonaldehyde 
• 137238-71-2 (4R)-3-[2-(Phenylmethoxy)acetyl]-4-(phenylmethyl)oxazolidin-2-one 

Downstream Products

• 154568-62-4 (4S,5S)-5-benzyloxy-6-tert-butyldiphenylsiloxyhex-2-en-3-ol 
• 154568-63-5 (2S,3S)-1-tert-butyldiphenylsiloxyhex-4-ene-2,3-diol 
• 154459-12-8 (2S,3S)-2-benzyloxyhex-4-ene-1,3-diol 
• 164164-48-1 (6S,7S,8R,8aR)-6-Benzyloxy-7-(tert-butyl-diphenyl-silanyloxy)-8-hydroxy-hexahydro-oxazolo[3,4-a]pyridin-3-one 
• 164164-41-4 C₃₇H₅₃NO₄Si₂ 
• 164164-42-5 (3S,4S,5R,6S,8S)-3-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxymethyl)-4-(tert-butyl-diphenyl-silanyloxy)-6-methyl-7-oxa-1-aza-bicyclo[3.2.1]octane 
• 164164-44-7 (2S,3R,4S,5S)-5-Benzyloxy-4-(tert-butyl-diphenyl-silanyloxy)-3-((S)-1-hydroxy-ethyl)-2-hydroxymethyl-piperidine-1-carboxylic acid methyl ester 
• 164164-45-8 (6S,7S,8R,8aS)-6-Benzyloxy-7-(tert-butyl-diphenyl-silanyloxy)-8-((S)-1-hydroxy-ethyl)-hexahydro-oxazolo[3,4-a]pyridin-3-one 
• 164164-47-0 (6S,7R,8aR)-6-Benzyloxy-7-(tert-butyl-diphenyl-silanyloxy)-tetrahydro-oxazolo[3,4-a]pyridine-3,8-dione 
• 164164-46-9 (6S,7S,8aS)-6-Benzyloxy-7-(tert-butyl-diphenyl-silanyloxy)-8-eth-(E)-ylidene-hexahydro-oxazolo[3,4-a]pyridin-3-one 
• 164164-39-0 (E)-(2R,3S)-2-Benzyloxy-3-(tert-butyl-diphenyl-silanyloxy)-hex-4-enoic acid methoxy-methyl-amide 
• 164164-43-6 [(3S,4S,5R,6S,8S)-3-Benzyloxy-4-(tert-butyl-diphenyl-silanyloxy)-6-methyl-7-oxa-1-aza-bicyclo[3.2.1]oct-8-yl]-methanol 
• 164164-40-3 (E)-(2S,3S)-2-Benzyloxy-3-(tert-butyl-diphenyl-silanyloxy)-hex-4-enal oxime 

Relevant academic research and scientific papers

Synthesis of Medium Ring Ethers. Part 4. Stereoselective Claisen-mediated Ring Expansion as a Route to Homochiral Disubstituted Medium Ring Lactones

Thermal elimination/Claisen rearrangement of selenoxides derived from the enantiomerically pure phenylselenomethyl-substituted cyclic acetals 4 and 8 proceeds stereospecifically to provide the homochiral 8- and 7-membered lactones 5 and 9 respectively.