154479-69-3

Upstream product

• 62-53-3 aniline 
• 118209-48-6 ethyl 1-(3-nitrophenyl)-1,4-pentanedione-3-carboxylate 
• 2227-64-7 3'-nitro-2-bromoacetophenone 
• 154479-68-2 1-(3-nitro-phenyl)-pentane-1,4-dione 

Downstream Products

• 154479-76-2 2-(3-Azido-phenyl)-5-methyl-1-phenyl-1H-pyrrole 
• 154479-72-8 3-(5-Methyl-1-phenyl-1H-pyrrol-2-yl)-phenylamine 

Relevant academic research and scientific papers

An efficient procedure for the synthesis of polysubstituted pyrroles in an ionic liquid

The ionic liquid 1-butyl-3-methyl-imidazolium hydrogen sulfate, [bmim]HSO4, was used as a catalyst and reaction medium for the pyrrole synthesis, and a wide range of aliphatic, aromatic, heteroaromatic and carboxylic 1,4-diketones easily underwent condensations with aniline and ethylenediamine to form polysubstituted pyrroles. Sequential decarboxylation/Paal-Knorr pyrrole condensation was observed, which provides a new and facile approach to monoester pyrroles from 1,4-diketo-2,3-dicarboxylic acid esters.

Polycondensed Nitrogen Heterocycles. Part 25. Aminopyrrolophenanthridines by Decomposition of 2-(3-Azidophenyl)-1-arylpyrroles

Acid catalyzed decomposition of the azido derivatives 4a-c give rise to amino-hydroxy-phenylpyrroles of type 7 and 8 upon hydrolysis of the intermediate aryl nitrenium ions, together with the hydrogen abstraction compounds of type 3.The aminopyrrolo1,2-f