154533-84-3Relevant academic research and scientific papers
Synthesis of N-allylhydroxamic Acids via -Sigmatropic Rearrangement
Torret, J. A. De la,Fernandez, M.,Morgans, D.,Smith, David B.,Talamas, F. X.,Trejo, A.
, p. 15 - 18 (2007/10/02)
N-allylhydroxamic acids 3 can be prepared by a novel thermal -rearrangement of appropriate precursor O-tetrahydropyranylhydroximates 2.Such compounds are available from the protected hydroximoyl chlorides via alkoxide displacement.The rearrangement can proceed with modest chirality transfer.
