154601-17-9Relevant academic research and scientific papers
CuCl2-mediated reaction of [60]fullerene with amines in the presence or absence of dimethyl acetylenedicarboxylate: Preparation of fulleropyrroline or aziridinofullerene derivatives
Yang, Hai-Tao,Liang, Xi-Chen,Wang, Yan-Hong,Yang, Yang,Sun, Xiao-Qiang,Miao, Chun-Bao
, p. 11992 - 11998 (2013)
The CuCl2-mediated three-component reaction of C60 with amines and dimethyl acetylenedicarboxylate afforded the fulleropyrrolines in moderate yields. Furthermore, the CuCl2-mediated oxidative [2 + 1] reaction of C60 with aromatic amines bearing a strong electron-withdrawing group provided the aziridinofullerenes and the selective cis-1-bisaziridinofullerenes.
Solvent-free synthesis of enamines from alkyl esters of propiolic or but-2-yne dicarboxylic acid in a ball mill
Thorwirth, Rico,Stolle, Achim
supporting information; experimental part, p. 2200 - 2202 (2011/11/06)
A solvent-free method for the addition of amines to dialkylacetylendicarboxylates or alkylpropiolates using a planetary ball mill was developed. Conversion of educts was quantitative within five minutes without use of any catalyst or base. Beside the E-/Z
Synthesis of aza-Henry products and enamines in water by Michael addition of amines or thiols to activated unsaturated compounds
Ziyaei-Halimehjani, Azim,Saidi, Mohammad R.
, p. 1244 - 1248 (2008/09/17)
Nitroamines and nitrothiols were synthesized in high yields by the Michael addition of amines and thiols to nitroolefins without using any catalyst. Also, the reaction of amines with dimethylacetylene dicarboxylate (DMAD) in water afforded the corresponding enamines.
