154634-82-9

Upstream product

• 882-33-7 diphenyldisulfane 
• 154634-81-8 (1R,2S,5S,6R,7S)-(+)-4-(but-3'-ynyl)-5-methoxy-4-azatricyclo<5.2.1.0^2,6>dec-8-en-3-one 
• 139750-90-6 (1R,2S,5R/S,6R,7S)-(+)-4-(but-3'-ynyl)-5-hydroxy-4-azatricyclo<5.2.1.0^2,6>dec-8-en-3-one 

Downstream Products

• 3348-73-0 (+)-laburnine 
• 139751-01-2 S-phenyl (1S,2R,3R,4S,9S,10R)-(+)-8-oxo-7-azatetracyclo<8.2.1.0^2,9.0^3,7>tridec-11-ene-4-carbothioate 

Relevant academic research and scientific papers

Enantioselective Synthesis of (+)-Indolizidine, (+)-Laburnine and (+)-Elaeokanines A and C using the Diels-Alder Reaction of α-(2-eyo-Hydroxy-10-bornylsulfinyl)maleimide

The Diels-Alder adduct 5 derived from the N-butynylmaleimide 6 and cyclopentadiene has been transformed into the tetracyclic lactams 12 and 19 via a common precursor 9.The lactams 12 and 19 have been converted into (+)-indolizidine 1 and (+)-laburnine 2, respectively, via retro-Diels-Alder reaction.Similar methodology has bee succesfully applied to the synthesis of (+)-elaeokanine A 3 and (+)-elaeokanine C 4.