154641-59-5Relevant academic research and scientific papers
Radical, one-step approach to o-chlorophenyl thioethers from xanthates. A rapid access to vinylsilanes
Corbet, Matthieu,Ferjancic, Zorana,Quiclet-Sire, Beatrice,Zard, Samir Z.
supporting information; experimental part, p. 3579 - 3582 (2009/05/07)
(Chemical Equation Presented) Xanthates have been readily converted into o-chlorophenyl thioethers using a one-step procedure conducted under radical conditions. In some selected cases, these aryl thioethers were successfully oxidized to the corresponding sulfoxides and sulfenic acid elimination afforded the corresponding vinylsilanes.
