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154746-92-6

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154746-92-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 154746-92-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,5,4,7,4 and 6 respectively; the second part has 2 digits, 9 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 154746-92:
(8*1)+(7*5)+(6*4)+(5*7)+(4*4)+(3*6)+(2*9)+(1*2)=156
156 % 10 = 6
So 154746-92-6 is a valid CAS Registry Number.

154746-92-6Downstream Products

154746-92-6Relevant articles and documents

Iron-catalyzed oxyfunctionalization of aliphatic amines at remote benzylic C-H sites

Mbofana, Curren T.,Chong, Eugene,Lawniczak, James,Sanford, Melanie S.

supporting information, p. 4258 - 4261 (2016/09/09)

We report the development of an iron-catalyzed method for the selective oxyfunctionalization of benzylic C(sp3)-H bonds in aliphatic amine substrates. This transformation is selective for benzylic C-H bonds that are remote (i.e., at least three carbons) from the amine functional group. High site selectivity is achieved by in situ protonation of the amine with trifluoroacetic acid, which deactivates more traditionally reactive C-H sites that are α to nitrogen. The scope and synthetic utility of this method are demonstrated via the synthesis and derivatization of a variety of amine-containing, biologically active molecules.

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