154850-66-5

Upstream product

• 604-69-3 β-D-glucose pentaacetate 
• 556-82-1 3-methyl-2-buten-1-ol 
• 53270-12-5 1,2-O-(1-ethoxyethylene) 3,4,6-tri-O-benzyl-1-thio-α-D-glucopyranose 
• 3254-17-9 3,4,6-tri-O-acetyl-1,2-O-(1-ethoxyethylidene)-α-D-glucopyranose 
• 53604-68-5 1,2-O-(1-ethoxyethylidene)-α-D-glucopyranose 
• 88988-46-9 2-O-acetyl-3,4,6-tetra-O-benzyl-α-D-glucopyranose 
• 108869-64-3 3,4,6-tri-O-benzyl-2-O-acetyl-α-D-glucosyl trichloroimidate 

Relevant academic research and scientific papers

ONE-POT SYNTHESIS OF SUBSTITUTED ALLYL-α-D-GLUCOPYRANOSIDES BY AN in situ ANOMERIZATION PROTOCOL

A new 3-step, 1-pot procedure for the stereoselective α-glycosylation of substituted allylic alcohols has been developed.The key step involves an in situ anomerization of the β-glycoside, obtained by Schmidt's glycosylation method, upon treatment with TiCl4.