15487-82-8Relevant articles and documents
Synthesis and structure of the donor-free potassium silanide K[SiPh3]
Alig, Edith,Georg, Isabelle,S?nger, Inge,Fink, Lothar,Wagner, Matthias,Lerner, Hans-Wolfram
, p. 153 - 158 (2019/01/29)
The donor-free potassium silanide K[SiPh3] was prepared by the reaction of hexaphenyldisilane, Ph3Si-SiPh3, with potassium metal in benzene at room temperature. The solid-state structure, determined by powder X-ray diffrac
Carbanion mechanisms XVIII. Generation of silyl anions by nucleophilic cleavage of disilanes
Buncel, Erwin,Venkatachalam, T. Krishnan,Edlund, U.
, p. 85 - 89 (2007/10/02)
Organosilyl potassium compounds are conveniently generated by cleavage of hexaorganodisilanes with potassium t-butoxide in common solvents other than HMPA (i.e. in THF or DME).Nucleophilic attack on unsymmetrical disilanes results in formation of the more
PHOTOINDUCED ELECTRON TRANSFER FROM TRIPHENYLMETHYL ANION OR TRIPHENYLSILYL ANION TO p-TERPHENYL
Ito, Osamu,Aruga, Tamotsu,Matsuda, Minoru
, p. 2259 - 2264 (2007/10/02)
The steady illumination of triphenylsilyl anion and p-terphenyl (p-TP) in tetrahydrofuran yielded the radical anion of p-terphenyl (p-TP.-), which persisted after cutting of the light.When the triphenylmethylanion was used, p-TP.- wa
