15487-82-8

Upstream product

• 1450-23-3 hexaphenyldisilane 
• 865-47-4 potassium tert-butylate 
• 1829-41-0 methoxy-triphenyl-silane 
• 301181-44-2 triphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane 
• 789-25-3 HSiPh₃ 
• 1450-22-2 methylpentaphenyldisilane 
• 1450-20-0 2,2-Dimethyl-1,1,1,2-tetraphenyldisilan 
• 1450-18-6 1,1,1-trimethyl-2,2,2-triphenyldisilane 
• 76-86-8 Triphenylsilyl chloride 
• 1516-80-9 ethoxytriphenylsilane 
• 18870-36-5 (1-methyl-1-phenyl-ethyl)-triphenyl-silane 
• 1048-08-4 tetraphenylsilane 

Downstream Products

• 18763-47-8 ph3Si(OCH(4-toy)2) 
• 791-31-1 triphenylhydroxysilane 
• 18754-93-3 1,1,1-triethyl-2,2,2-triphenyl-disilane 
• 18834-05-4 9-ethyl-3-triphenylsilanyl-carbazole 
• 18858-75-8 triphenyl(4-methylphenyl)silan 
• 149792-82-5 2-chloro-1,1,1,3,3,3-hexaphenyltrisilane 
• 18856-13-8 2,2,-dimethyl-1,1,1,3,3,3-hexaphenyltrisilane 
• 789-25-3 HSiPh₃ 
• 1048-08-4 tetraphenylsilane 
• 1450-23-3 hexaphenyldisilane 
• 18909-18-7 1-diphenylmethylene-4-trityl-2,5-cyclohexadiene 
• 18536-57-7 1,1,1-trichloro-2,2,2-triphenyl-disilane 
• 6928-70-7 triphenylstannyltriphenylsilane 
• 149033-91-0 ClPh₂GeSiPh₃ 

Relevant academic research and scientific papers

Synthesis and structure of the donor-free potassium silanide K[SiPh3]

The donor-free potassium silanide K[SiPh3] was prepared by the reaction of hexaphenyldisilane, Ph3Si-SiPh3, with potassium metal in benzene at room temperature. The solid-state structure, determined by powder X-ray diffrac

Boron-metal exchange reaction of silylboranes with organometallic reagents: A new route to arylsilyl anions

The boron-metal exchange reaction of (arylsilyl)boranes with alkyllithiums, potassium tert-butoxide, and methylmagnesium bromide affords the corresponding silyllithium, silylpotassium, and silylmagnesium compounds, respectively. Especially, the boron-lithium exchange reaction occurs even in hydrocarbon solvents such as toluene and hexane as well as in THF.

Carbanion mechanisms XVIII. Generation of silyl anions by nucleophilic cleavage of disilanes

Organosilyl potassium compounds are conveniently generated by cleavage of hexaorganodisilanes with potassium t-butoxide in common solvents other than HMPA (i.e. in THF or DME).Nucleophilic attack on unsymmetrical disilanes results in formation of the more

Les triorganosilylpotasium: nouvelle voie d'acces et quelques aspects de leur reactivite

We report here a new procedure for the convenient and easy preparation of silylanions and especially of Me3Si-.These undergo coupling reaction with halides and α-enone in good yields.Reactions with 5-bromo-1 hexene, benzophenone and carbon dioxide provide evidence for the ability of the silylpotassium to act as monoelectron transfer reagents.The course of these reactions varies substantially with the nature of the solvent.

PHOTOINDUCED ELECTRON TRANSFER FROM TRIPHENYLMETHYL ANION OR TRIPHENYLSILYL ANION TO p-TERPHENYL

The steady illumination of triphenylsilyl anion and p-terphenyl (p-TP) in tetrahydrofuran yielded the radical anion of p-terphenyl (p-TP.-), which persisted after cutting of the light.When the triphenylmethylanion was used, p-TP.- wa