154913-83-4Relevant academic research and scientific papers
Stereoselective Synthesis of Alcohols, XLIII. Asymmetric Induction on the Intramolecular Allylboration Reaction of (8-Oxo-2-octenyl)boronates
Hoffmann, Reinhard W.,Sander, Thomas
, p. 1185 - 1192 (2007/10/02)
The cyclization of (8-oxo-2-octenyl)boronates having methyl substituents in the chain linking the two functional groups proceeds with complete simple diastereoselectivity and with induced diastereoselectivity of 85 to >98percent to give methyl-substituted 2-vinylcyclohexanols. - Key Words: Cyclization, stereoselective / Allylboration, intramolecular / Boronates
