15492-92-9

Basic information

• Product Name: (C₆H₅)3BiMo(CO)3(C₁₂H₈N₂)
• CAS NO: 15492-92-9
• Molecular Weight: 800.478
• Mol File: 15492-92-9.mol

Chemical Properties

• CAS DataBase Reference: (C₆H₅)3BiMo(CO)3(C₁₂H₈N₂)(CAS DataBase Reference)
• NIST Chemistry Reference: (C₆H₅)3BiMo(CO)3(C₁₂H₈N₂)(15492-92-9)
• EPA Substance Registry System: (C₆H₅)3BiMo(CO)3(C₁₂H₈N₂)(15492-92-9)

Safety Data

• Hazardous Substances Data: 15492-92-9(Hazardous Substances Data)

Upstream product

• 15740-78-0 (1,10-phenanthroline)molybdenum tetracarbonyl 
• 603-33-8 triphenylbismuthane 

Relevant articles and documents

Mixed complexes of group VIb metal carbonyls

Forty-nine new mixed derivatives - which contain two different noncarbonyl substituent groups - of the group VIb metal carbonyls are reported. These are of the types M(CO)3X2Y and M(CO)2X2Y2 where M = Cr, Mo, W; X2 = 2,2′-dipyridyl (dipy) or o-phenanthroline (phen); and Y = various monodentate Lewis bases. Carbonyl stretching frequencies for many derivatives containing strongly π-accepting Y ligands yield complex Cotton-Kraihanzel force constants; real force constants may be obtained if the two physically different cis-CO-CO interactions are differentiated in a physically reasonable way. Evidence is presented that N,N′-dimethylformamide (DMF) and acetamide exhibit normal coordination through oxygen in the complexes Mo(CO)3(phen)(DMF) and Mo(CO)3(phen)(acetamide).