154952-68-8

Basic information

• Product Name: (1'S,4'S,5'S)-2-<4'-<3-(tert-Butyldimethylsilyloxy)-2,2-dimethylpropyl>-5'-(4-methoxybenzyloxy)-2'-methylcyclopent-2'-enyl>acetaldehyd
• Synonyms: (1'S,4'S,5'S)-2-<4'-<3-(tert-Butyldimethylsilyloxy)-2,2-dimethylpropyl>-5'-(4-methoxybenzyloxy)-2'-methylcyclopent-2'-enyl>acetaldehyd
• CAS NO: 154952-68-8
• Molecular Weight: 460.729
• Mol File: 154952-68-8.mol

Chemical Properties

• CAS DataBase Reference: (1'S,4'S,5'S)-2-<4'-<3-(tert-Butyldimethylsilyloxy)-2,2-dimethylpropyl>-5'-(4-methoxybenzyloxy)-2'-methylcyclopent-2'-enyl>acetaldehyd(CAS DataBase Reference)
• NIST Chemistry Reference: (1'S,4'S,5'S)-2-<4'-<3-(tert-Butyldimethylsilyloxy)-2,2-dimethylpropyl>-5'-(4-methoxybenzyloxy)-2'-methylcyclopent-2'-enyl>acetaldehyd(154952-68-8)
• EPA Substance Registry System: (1'S,4'S,5'S)-2-<4'-<3-(tert-Butyldimethylsilyloxy)-2,2-dimethylpropyl>-5'-(4-methoxybenzyloxy)-2'-methylcyclopent-2'-enyl>acetaldehyd(154952-68-8)

Safety Data

• Hazardous Substances Data: 154952-68-8(Hazardous Substances Data)

Upstream product

• 154952-67-7 (1'S,4'S,5'S)-(+)-2-<4'-<3-(tert-Butyldimethylsilyloxy)-2,2-dimethylpropyl>-5'-(4-methoxybenzyloxy)-2'-methylcyclopent-2'-enyl>ethanol 
• 154952-66-6 (1'S,4'S,5'S)-2-<4'-<3-(tert-Butyldimethylsilyloxy)-2,2-dimethylpropyl>-5'-(4-methoxybenzyloxy)-2'-methylcyclopent-2'-enyl>essigsaeure 

Downstream Products

• 154952-71-3 (1'S,4'S,5'S)-2-<4'-<3-(tert-Butyldimethylsilyloxy)-2,2-dimethylpropyl>-5'-(4-methoxybenzyloxy)-2'-methylcyclopent-2'-enylmethyl>-2-(trimethylsilyl)ethinyl-1,3-dioxolan 
• 154952-70-2 (1'S,4'S,5'S)-1-<4'-<3-(tert-Butyldimethylsilyloxy)-2,2-dimethylpropyl>-5'-(4-methoxybenzyloxy)-2'-methylcyclopent-2'-enyl>-4-(trimethylsilyl)but-3-in-2-on 
• 154952-72-4 (1'S,4'S,5'S)-(+)-3-<4'-(2-Ethinyl-1,3-dioxolan-2-ylmethyl)-5'-(4-methoxybenzyloxy)-3'-methylcyclopent-2'-enyl>-2,2-dimethylpropan-1-ol 
• 154952-73-5 (1'S,4'S,5'S)-(-)-3-<4'-(2-Ethinyl-1,3-dioxolan-2-ylmethyl)-5'-(4-methoxybenzyloxy)-3'-methylcyclopent-2'-enyl>-2,2-dimethyl-propionaldehyd 
• 154952-74-6 C₂₅H₃₄O₅ 
• 154952-75-7 (3aR,3bR,4R,6aS,7S,7aS)-(+)-Decahydro-4-hydroxy-7-(4-methoxybenzyloxy)-3a,5,5-trimethyl-3-methylen-2H-cyclopentapentalen-2-on 
• 33404-85-2 (-)-Coriolin 

Relevant articles and documents

Radical-Type Cyclization of Diens, VI. - Total Synthesis of (-)-Coriolin and (-)-Epicoriolin from (S)-(+)-Carvone

(3aR,4S,6aS)-(+)-4-(4-Methoxybenzyloxy)-6a-methyl-3,3a,4,6a-tetrahydro-2H-cyclopentafuran-2-one (10) and (3aR,3bR,4R,6aS,7S,7aS)-(-)-decahydro-4,7-dihydroxy-3a,5,5-trimethyl-3-methylene-2H-cyclopentapentalen-2-one (21) are the key intermediates in t