15498-31-4

Basic information

• Product Name: 1,4-dioxecane-5,10-dione
• Synonyms: 1,4-dioxecane-5,10-dione;1,4-Dioxacyclodecane-5,10-dione;Adipic acid ethylene ester;Einecs 239-527-8
• CAS NO: 15498-31-4
• Molecular Formula: C₈H₁₂O₄
• Molecular Weight: 172.17848
• EINECS: 239-527-8
• Mol File: 15498-31-4.mol

Chemical Properties

• Boiling Point: 408.5°Cat760mmHg
• Flash Point: 220.7°C
• Appearance: /
• Density: 1.129g/cm³
• Vapor Pressure: 6.97E-07mmHg at 25°C
• Refractive Index: 1.442
• CAS DataBase Reference: 1,4-dioxecane-5,10-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-dioxecane-5,10-dione(15498-31-4)
• EPA Substance Registry System: 1,4-dioxecane-5,10-dione(15498-31-4)

Safety Data

• Hazardous Substances Data: 15498-31-4(Hazardous Substances Data)

Usage

Uses

Used in Pharmaceutical Industry:
1,4-Dioxecane-5,10-dione is used as a key intermediate for the synthesis of various drugs, including antibiotics, antifungals, and antiparasitic agents, due to its ability to form complex molecular structures that exhibit therapeutic properties.
Used in Polymer Production:
1,4-Dioxecane-5,10-dione is utilized as a precursor in the production of polymers, contributing to the development of materials with specific properties for various applications.
Used in Organic Chemistry:
As a reagent in organic chemistry reactions, 1,4-Dioxecane-5,10-dione facilitates the synthesis of complex organic compounds, enabling the creation of new molecules with potential applications in medicine, materials science, and chemical synthesis.
It is important to handle 1,4-Dioxecane-5,10-dione with caution due to its potential health hazards and reactivity, ensuring safe practices in its use across different industries.

InChI:InChI=1/C8H12O4/c9-7-3-1-2-4-8(10)12-6-5-11-7/h1-6H2

Upstream product

• 107-21-1 ethylene glycol 
• 111-50-2 Adipic acid dichloride 
• 124-04-9 Adipic acid 
• 693-34-5 fluorure d'acide adipique 
• 90073-98-6 C₃₈H₃₄O₂Sn₂ 

Relevant articles and documents

Does diatomic sulfur (S2) react as a free species?

A detailed study into the design and synthesis of stable 1,2-dithietane derivatives for the generation of diatomic sulfur (S2) was undertaken. Computer-aided evaluation of enthalpic differences was used to direct the synthesis of target compounds and, although all of the compounds calculated to afford S2 that were prepared did yield diatomic sulfur, an isolable 1,2-dithietane other than dithiatopazine failed to materialize. The results of this study provide convincing evidence that the computational procedure outlined can be successfully used to predict the course of S2 extrusion pathways from potential dithionocarbonylated derivatives. To determine if the disulfide moiety found in the Diels-Alder adduct derived from the addition of diatomic sulfur to conjugated 1,3-dienes is due to a transference mechanism involving the transient 1,2-dithietane intermediate, a chiral nonracemic binaphthyl source of S2 was prepared. Reactions of S2 from this source with chiral nonracemic and prochiral conjugated 1,3-dienes indicate that the added disulfide moiety would be inconsistent with a transference mechanism and that a "free" acting S2 unit is more likely to be involved.

SYNTHESE DE DILACTONES MACROCYCLIQUES ASSISTEE PAR LES ORGANOSTANNIQUES APPLICATION AUX MACROCYCLES SOUFRES (SULFURES, SULFOXYDES, DISULFURES) COMPLEXATION SELECTIVE DE L'ION Ca(2+)

Tin "template driven" condensation of diacid fluorides with triphenyltin derivatives of diols affords macrocyclic dilactones in good yields.The reaction proceeds at moderate dilution conditions from diacids and diols without isolation of the intermediate activated species.The dilution, temperature and ring-size effects on this reaction are detailed.This method is applied to the praparation of sulfur-, disulfide- and sulfoxide-containing macrocyclic dilactones, as well as to the preparation of chiral macrocycles derived from α-aminoacids.The binding abilities of these twelve new ligands (12- to 21-membered rings) are estimated by picra te extraction from water to chloroform.Selective complexation for calcium is found in some cases.