155-25-9 Usage
Chemical Properties
Amitrole is a colorless to off-white crystalline
solid or white powder. Odorless when pure.
Potential Exposure
A potential danger to those involved
in the manufacture, formulation, and application of this
postemergence herbicide, which is now limited to noncrop
applications as a herbicide and plant growth regulator.
Some triazoles have been used as rubber components.
Shipping
UN2588 Pesticides, solid, toxic, Hazard Class:
6.1; Labels: 6.1-Poisonous materials, Technical Name
Required. UN3077 Environmentally hazardous substances,
solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous
material, Technical Name Required.
Incompatibilities
Dust may be explosive in air. Keep
away from strong oxidizers; strong acids; light and heat
(decomposes). Corrosive to iron, aluminum, and copper.
Sublimes undecomposed at reduced pressure.
Waste Disposal
Consult with environmental
regulatory agencies for guidance on acceptable disposal
practices. Generators of waste containing this contaminant
(≥100 kg/mo) must conform with EPA regulations governing
storage, transportation, treatment, and waste disposal.
Amitrol is resistant to hydrolysis and the action of oxidizing
agents. Burning the compound with polyethylene is
reported to result in .99% decomposition.
Check Digit Verification of cas no
The CAS Registry Mumber 155-25-9 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,5 and 5 respectively; the second part has 2 digits, 2 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 155-25:
(5*1)+(4*5)+(3*5)+(2*2)+(1*5)=49
49 % 10 = 9
So 155-25-9 is a valid CAS Registry Number.
InChI:InChI=1/C2H4N4/c3-2-4-1-5-6-2/h1H,(H3,3,4,5,6)
155-25-9Relevant articles and documents
Kinetics and mechanism of uncatalyzed and ruthenium(III)-catalyzed oxidation of formamidine derivative by hexacyanoferrate(III) in aqueous alkaline medium
FAWZY
, p. 733 - 743 (2016)
The catalytic effect of ruthenium(III) on the oxidation of N, N-dimethyl- N′-(4H-1,2,4-triazol- 3-yl) formamidine (ATF) by hexacyanoferrate(III) (HCF) was studied spectrophotometrically in aqueous alkaline medium. Both uncatalyzed and catalyzed reactions showed first order kinetics with respect to [HCF], whereas the reaction orders with respect to [ATF] and [OH ?] were apparently less than unity over the concentration range studied. A first order dependence with respect to [RuIII] was obtained. Increasing ionic strength increased the rate of uncatalyzed reaction and decreased the rate of the catalyzed one Plausible mechanistic schemes of oxidation reactions have been proposed. In both cases, the final oxidation products are identified as aminotriazole, dimethyl amine and carbon dioxide. The rate laws associated with the reaction mechanisms are derived. The reaction constants involved in the different steps of the mechanisms were calculated. The activation and thermodynamic parameters have been computed and discussed. [Figure not available: see fulltext.]