1551314-94-3Relevant academic research and scientific papers
Synthesis method of [60] fullerene and seven-membered nitrogen heterocycle derivatives
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Paragraph 0059; 0060; 0061; 0062; 0063; 0064; 0076-0077, (2017/02/24)
The invention provides a synthesis method of [60] fullerene and seven-membered nitrogen heterocycle derivatives. The method takes C60 and N-sulfonyl-O-amino-acetophenones compounds or N-sulfonyl-O-amino-acetophenone O-methyl oximes compounds as reaction r
Synthesis of [60]Fullerene-Fused tetrahydroazepinones and azepinonimines via cu(oac)2-promoted n -heteroannulation reaction
Liu, Tong-Xin,Zhang, Zhenbei,Liu, Qingfeng,Zhang, Pengling,Jia, Penghao,Zhang, Zhiguo,Zhang, Guisheng
supporting information, p. 1020 - 1023 (2014/03/21)
A convenient and efficient Cu(OAc)2-mediated N-heteroannulation reaction of [60]fullerene with N-sulfonylated o-amino-aromatic methyl ketones or O-alkyl oximes has been reported for the synthesis of novel and scarce [60]fullerene-fused tetrahydroazepinones and -azepinonimines in a highly selective manner. Moreover, a possible mechanism involving two pathways is proposed on the basis of the experimental observations.
