155197-75-4Relevant academic research and scientific papers
Double stannylation d'un sulfure propargylique par l'hydrure de tributyletain en presence de thiol
Lambert, Marie-Pierre,Ratier, Max,Duboudin, Jean-Georges,Petraud, Michel
, p. 181 - 188 (2007/10/02)
In the presence of small amounts of p-thiocresol, hydrostannylation of propargyl p-tolyl sulfide promotes the unexpected formation of (Z)-1,2-bis(organostannyl)olefin instead of yielding normal addition products.The application of a non-refocusing INEPT pulse sequence in 119Sn NMR spectroscopy allows the determination of its stereochemistry by comparison of observed patterns with calculated spectra.Key words: Hydrostannylation; Nuclear magnetic resonance; INEPT; Propargyl sulfides
