155209-26-0Relevant academic research and scientific papers
Metal Complexes with Biological Important Ligands, LXIX. Half-Sandwich Complexes of Cobalt(III), Rhodium(III), Iridium(III) and Ruthenium(II) with Anions of α-Hydroxyimino Acids
Lampeka, Rostislav,Bergs, Ralph,Kraemer, Roland,Polborn, Kurt,Beck, Wolfgang
, p. 225 - 232 (2007/10/02)
and have been obtained by reactions of (η5-C5Me5)Co(CO)I2, 5-C5Me5)MCl2>2 (M = Rh, Ir) and 6-p-cymene)RuCl2>2 with 2-hydroxyiminocarboxylates.These complexes are also accessible by template synthesis from hydroxylamine or O-methylhydroxylamine, α-oxocarboxylate and (η5-C5Me5)Co(CO)I2 or 5-C5Me5)MCl2>2 (M = Rh, Ir).The structure of the SRu enantiomer of has been determined by X-ray diffraction. - Keywords: Cobalt, Rhodium, Iridium, Ruthenium, 2-Hydroxyiminocarboxylate
