1552276-07-9

Upstream product

• 376357-56-1 1-(tert-butyl-diphenyl-silanyloxy)-4-methyl-pent-4-en-2-ol 
• 106731-74-2 tert-butyl[(2S)-oxiran-2-ylmethoxy]diphenylsilane 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 1552276-09-1 (2S,4S)-1-(tert-butyldiphenylsilyloxy)-4-methylhex-5-ene-2,4-diol 
• 1552276-11-5 (2S,4R)-1-(tert-butyldiphenylsilyloxy)-4-methylhex-5-ene-2,4-diol 
• 1552276-13-7 C₃₀H₃₆O₃Si 
• 1552276-20-6 C₁₄H₁₆O₃ 
• 1552276-15-9 ((2R,4S,6S)-6-methyl-2-phenyl-6-vinyl-1,3-dioxan-4-yl)methanol 

Relevant academic research and scientific papers

Synthetic studies on polymaxenolides: Model studies for constructing dihydropyran portion and synthesis of lower portion

With a goal of the total synthesis of polymaxenolide, the first hybrid marine natural product, the model studies for constructing the dihydropyran portion based on the originally proposed biosynthesis (C-C bond formation followed by dehydrative cyclization) and the synthesis of the lower portion (the C1-C3, C7-C17 portion) based on an iodide-induced Morita-Baylis-Hillman type reaction (a three-component assembly) followed by Suzuki-Miyaura cross-coupling are described.