155257-69-5Relevant articles and documents
Exploiting Steric Shielding : Tuning Terpenoid-Derived Oxazolidin-2-ones as Chiral Auxiliarites for the Diels-Alder Reaction
Banks, Malcolm R.,Blake, Alexander J.,Brown, Angus R.,Cadogan, J. I. G.,Gaur, Suneel,et al.
, p. 489 - 492 (1994)
Preparative metodology is described for acces to three different terpenoid-derived oxazolidin-2-ones 4,8,and 11, of which the latter, obtained from camphene in four steps, provides virtualy complete asymmetric induction when acting as a chiral auxilarity in Diels-Alder cycloaddition reactions with cyclopentadiene.