155354-49-7Relevant academic research and scientific papers
Formation of Cyclohexanes in the Palladium Catalyzed Reaction of ε-Unsaturated Cyano Esters and Congeners
Bouyssi, D.,Coudanne, I.,Uriot, H.,Gore, J.,Balme, G.
, p. 8019 - 8022 (1995)
A previously described palladium-catalyzed cyclization leading to cyclopentane derivatives has been extended to the formation of cyclohexanes by disfavoring the competing Heck reaction.The nature of the nucleophile plays a prominent part in this generalization.
Intramolecular Ring Opening of Epoxides by Bis-Activated Carbanions. The Influence of Ring Size on Reactivity and Selectivity
Benedetti, Fabio,Berti, Federico,Fabrissin, Silvio,Gianferrara, Teresa
, p. 1518 - 1524 (2007/10/02)
A quantitative study on the effect of ring size in the intramolecular ring opening of epoxides by carbanions is described.Two series of substrates were examined: α,α-bis-sulfonyl ω-epoxides 1 and α-cyano-α-sulfonyl ω-epoxides 2; in each series the carbani
