155446-90-5Relevant academic research and scientific papers
Stereocontrolled Synthesis of 3'-Isomeric β-Nucleoside by Intramolecular Glycosylation
Sujino, Keiko,Sugimura, Hideyuki
, p. 2541 - 2542 (1994)
Intramolecular glycosylation of a pyrimidine derivative, which was temporarily connected to a 2,3-unsaturated 1-thiopentofuranoside through an etheral linkage, led to an unusual 3'-isomeric nucleoside in a stereoselective fashion.
Stereocontrolled synthesis of pyrimidine 2',3'-dideoxy-β-nucleosides by intramolecular glycosylation
Sujino,Sugimura
, p. 1883 - 1886 (2007/10/02)
β-2',3'-Dideoxynucleosides and their 3'-azido and 3'-fluoro substituted derivatives were synthesized in a stereocontrolled manner by the dimethyl(methylthio)sulfonium tetrafluoroborate promoted intramolecular glycosylation of phenyl 2,3-dideoxy-5-O-(2-pyrimidyl)-1-thioglycosides followed by hydrolysis or ammonolysis.
