155570-15-3

Basic information

• Product Name: 1-<(N,N-dimethylamino)methyl>-2-benzene
• Synonyms: 1-<(N,N-dimethylamino)methyl>-2-benzene
• CAS NO: 155570-15-3
• Molecular Weight: 381.856
• Mol File: 155570-15-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-<(N,N-dimethylamino)methyl>-2-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-<(N,N-dimethylamino)methyl>-2-benzene(155570-15-3)
• EPA Substance Registry System: 1-<(N,N-dimethylamino)methyl>-2-benzene(155570-15-3)

Safety Data

• Hazardous Substances Data: 155570-15-3(Hazardous Substances Data)

Upstream product

• 5565-32-2 chlorotris(trimethylsilyl)silane 
• 56174-66-4 2-(N,N-dimethylaminomethyl)phenyllithium 

Downstream Products

• 1450-14-2 1,1,1,2,2,2-hexamethyldisilane 

Relevant articles and documents

Chemical and photochemical approaches to amino(aryl) silylenes

Generation by two different methods of silylenes stabilized by o-amino(aryl) groups is reported.The halodemetallation of difluoro- or dichloro-silanes with Li metal or lithium-naphthalene gave the same product, a stabilized sila-ylide (hypercoordinated silylene).Intramolecular Lewis base stabilization is not sufficient to isolate a monomeric species.The silylenes, however, have been trapped with 2,3-dimethylbutadiene.An unexpected intramolecular rearrangement to silaacenaphthene has been observed in the case of a six-membered ring amino(aryl) coordinated silylene.Photolysis of o-1--2-benzene produced, among other products, Me3SiSiMe3 and the sila-ylide, which has been trapped with Et3SiH and dimethylbutadiene.Our mechanistic interpretation is supported by spectral observation of the photochemically generated reaction intermediates in a 3-methylpentane glass at low temperature. Key words: Silylene; Sila-ylide; Amino-aryl; Alkali metals; Stabilization; Photochemistry