155583-03-2Relevant academic research and scientific papers
CARBANIONEN VON 2-(METHYLTHIO)THIAN UND 2-(METHYLTHIO)THIEPAN UND IHRE REAKTION MIT ELEKTROPHILEN
Boege, Askan,Schwaer, Gerhard,Voss, Juergen
, p. 175 - 182 (2007/10/02)
2-(Methylthio)thiane (2) and 2-(methylthio)thiepane (3) are deprotonated with butyllithium in the 2-position.The resulting carbanions react with electrophiles to form the 2-alkyl derivatives 10, carbinols 11 and 13, or the ketone 12.Key words: Thioacetals
