155607-16-2Relevant academic research and scientific papers
Synthesis of 2-C2Ph2)(CO)(P-i-Pr3)2> (M=Os or Ru) and X-ray crystal structure of the osmium derivative
Espuelas, Jesus,Esteruelas, Miguel A.,Lahoz, Fernando J.,Lopez, Ana M.,Oro, Luis A.,Valero, Cristina
, p. 223 - 228 (1994)
The tetrahydrido complex (1) reacts with diphenylacetylene to give cis- and trans-stilbene and 2-C2Ph2)(CO)(P-i-Pr3)2> (5).The X-ray crystal structure of 5 has been determined. 5 reacts with CO to give 2-C2Ph2)(CO)2(P-i-Pr3)2> (6).The related ruthenium complex 2-C2Ph2)(CO)(P-i-Pr3)2> (7) was obtained by reaction of 2-H2BH2)(CO)(P-i-Pr3)2> (8) with diphenylacetylene. 7 reacts with CO to give (9) and diphenylacetylene.The synthesis of the hydridovinyl complex (10) is also reported.Key words: Ruthenium; Osmium
