1557-66-0Relevant academic research and scientific papers
A novel application of (Diacetoxyiodo)benzene for carbon-carbon cleavage of aryl diamines and synthesis of quinones
Telvekar, Vikas N.,Bachhav, Harshal M.
, p. 2059 - 2062 (2010)
A novel synthetic utility of hypervalent iodine reagent, (diacetoxyiodo)benzene for diamino aryl carbon-carbon cleavage is described. 1,2-Diamino aryl compounds were successfully converted into the corresponding nitriles, while the developed method was also useful for the preparation of quinones from corresponding 1,4-diamino aryl compounds. The advantages of this protocol are shorter reaction times and mild reaction conditions to obtain moderate to good yields.
