Welcome to LookChem.com Sign In|Join Free

CAS

  • or

15570-12-4

Post Buying Request

15570-12-4 Suppliers

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier

15570-12-4 Usage

Chemical Properties

clear colorless to light yellow liquid

Uses

Different sources of media describe the Uses of 15570-12-4 differently. You can refer to the following data:
1. Labelled analogue 3-Methoxy cy as phencyclidine but differs in terms binding affinity. 3-Methoxy
2. 3-Methoxythiophenol is used in the preparation of allenes.

Check Digit Verification of cas no

The CAS Registry Mumber 15570-12-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,5,5,7 and 0 respectively; the second part has 2 digits, 1 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 15570-12:
(7*1)+(6*5)+(5*5)+(4*7)+(3*0)+(2*1)+(1*2)=94
94 % 10 = 4
So 15570-12-4 is a valid CAS Registry Number.
InChI:InChI=1/C7H8OS/c1-8-6-3-2-4-7(9)5-6/h2-5,9H,1H3/p-1

15570-12-4 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Alfa Aesar

  • (A10648)  3-Methoxythiophenol, 98%   

  • 15570-12-4

  • 1g

  • 224.0CNY

  • Detail
  • Alfa Aesar

  • (A10648)  3-Methoxythiophenol, 98%   

  • 15570-12-4

  • 5g

  • 519.0CNY

  • Detail
  • Alfa Aesar

  • (A10648)  3-Methoxythiophenol, 98%   

  • 15570-12-4

  • 25g

  • 1866.0CNY

  • Detail
  • Aldrich

  • (155705)  3-Methoxythiophenol  98%

  • 15570-12-4

  • 155705-5G

  • 920.79CNY

  • Detail
  • Aldrich

  • (155705)  3-Methoxythiophenol  98%

  • 15570-12-4

  • 155705-25G

  • 3,583.71CNY

  • Detail

15570-12-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-Methoxybenzenethiol

1.2 Other means of identification

Product number -
Other names m-methoxyphenylthiol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:15570-12-4 SDS

15570-12-4Synthetic route

3-methoxy-1-iodobenzene
766-85-8

3-methoxy-1-iodobenzene

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

Conditions
ConditionsYield
Stage #1: 3-methoxy-1-iodobenzene With copper(l) iodide; potassium carbonate; sulfur In N,N-dimethyl-formamide at 90℃; for 12h; Inert atmosphere;
Stage #2: With sodium tetrahydroborate In N,N-dimethyl-formamide at 40℃; Inert atmosphere; Cooling with ice;
89%
With sodiumsulfide nonahydrate; copper; ethane-1,2-dithiol In dimethyl sulfoxide at 100℃; for 20h; Inert atmosphere; Green chemistry;89%
With copper(l) iodide; thiourea; L-proline; sodium t-butanolate In dimethyl sulfoxide at 90℃; for 24h; Inert atmosphere;85%
1-methoxy-3-methylsulfanyl-benzene
2388-74-1

1-methoxy-3-methylsulfanyl-benzene

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

Conditions
ConditionsYield
With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydride; diethylamine In xylene for 6h; Heating;88%
m-Anisidine
536-90-3

m-Anisidine

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

Conditions
ConditionsYield
und ueber mehrere Stufen.Diazotization;
With hydrogenchloride; sodium nitrite Diazotization.man traegt in eine waessr. Loesung von xanthogensaurem Kalium bei 85-90grad ein und verseift den entstandenen Ester durch Kochen mit alkoh. Kalilauge;
(i) aq. NaNO2, aq. HCl, (ii) potassium ethylxanthate, (iii) KOEt, EtOH; Multistep reaction;
methoxybenzene
100-66-3

methoxybenzene

A

4-Methoxybenzenethiol
696-63-9

4-Methoxybenzenethiol

B

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

Conditions
ConditionsYield
With disulfur dichloride; carbon disulfide; aluminium amalgam Destillieren des Reaktionsprodukts unter wenig vermindertem Druck;
1-methoxy-3-methylsulfanyl-benzene
2388-74-1

1-methoxy-3-methylsulfanyl-benzene

A

3-methylsulfanylphenol
3463-03-4

3-methylsulfanylphenol

B

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

Conditions
ConditionsYield
With hydrogenchloride; sodium isopropanethiolate 1)sodium isopropanethiolate,HMPA,120 degC,2.5 h 2)hydrochloric acid; Yield given. Multistep reaction. Yields of byproduct given;
[Dimethylamino-(3-methoxy-phenylsulfanyl)-methylene]-dimethyl-ammonium; iodide

[Dimethylamino-(3-methoxy-phenylsulfanyl)-methylene]-dimethyl-ammonium; iodide

A

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

B

tetramethylurea
632-22-4

tetramethylurea

Conditions
ConditionsYield
at 20℃; Rate constant; pH=11;
[(3-methoxyphenyl)sulfanyl]acetic acid
3996-32-5

[(3-methoxyphenyl)sulfanyl]acetic acid

A

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

B

Glyoxilic acid
298-12-4

Glyoxilic acid

Conditions
ConditionsYield
With perchloric acid; sodium perborate; acetic acid at 24.9℃; Rate constant; Thermodynamic data; Mechanism; var. temp., ΔH(excit.), ΔS(excit.);
Ethyl-3-methoxyphenyl-disulfid
55975-74-1

Ethyl-3-methoxyphenyl-disulfid

A

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

B

ethanethiol
75-08-1

ethanethiol

Conditions
ConditionsYield
With triphenylphosphine In 1,4-dioxane; water at 30℃; Rate constant;
S-(3-methoxyphenyl) dimethylcarbamothioate
50667-88-4

S-(3-methoxyphenyl) dimethylcarbamothioate

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

Conditions
ConditionsYield
With potassium hydroxide In methanol Heating;
With sodium hydroxide In methanol
(3S,3aR,4S,6aR,9S,9aR,9bR)-4-Hydroxy-3-(3-methoxy-phenylsulfanylmethyl)-9-methyl-6-methylene-octahydro-azuleno[4,5-b]furan-2,8-dione
248584-43-2

(3S,3aR,4S,6aR,9S,9aR,9bR)-4-Hydroxy-3-(3-methoxy-phenylsulfanylmethyl)-9-methyl-6-methylene-octahydro-azuleno[4,5-b]furan-2,8-dione

A

grosheimin
22489-66-3

grosheimin

B

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

Conditions
ConditionsYield
With phosphate buffer In methanol at 37℃; pH=7.4; Kinetics; Hydrolysis;
[(3-methoxyphenyl)sulfanyl]acetic acid
3996-32-5

[(3-methoxyphenyl)sulfanyl]acetic acid

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

Conditions
ConditionsYield
With perchloric acid; pyridinium chlorochromate In water; acetic acid at 24.85 - 44.85℃; Kinetics; Oxidation;
carbon disulfide
75-15-0

carbon disulfide

methoxybenzene
100-66-3

methoxybenzene

disulfur dichloride

disulfur dichloride

amalgamated aluminium

amalgamated aluminium

A

4-Methoxybenzenethiol
696-63-9

4-Methoxybenzenethiol

B

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

Conditions
ConditionsYield
Destillation des entstandenen Oels unter wenig vermindertem Druck;
chloride of/the/ m-anisolesulfonic acid

chloride of/the/ m-anisolesulfonic acid

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

Conditions
ConditionsYield
With sulfuric acid; zinc
m-anisole-sulfonic acid chloride

m-anisole-sulfonic acid chloride

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

Conditions
ConditionsYield
With ethanol; zinc
hydrogenchloride
7647-01-0

hydrogenchloride

3-Methoxybenzenesulfonyl chloride
10130-74-2

3-Methoxybenzenesulfonyl chloride

zinc

zinc

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

O-methylresorcine
150-19-6

O-methylresorcine

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: (i) NaH, DMF, (ii) /BRN= 635823/
2: 280 °C
3: aq. NaOH / methanol
View Scheme
Multi-step reaction with 3 steps
1: (i) NaH, DMF, (ii) /BRN= 635823/
2: 270 °C
3: KOH / methanol / Heating
View Scheme
O-(3-methoxyphenyl) N,N-dimethylcarbamothioate
50667-83-9

O-(3-methoxyphenyl) N,N-dimethylcarbamothioate

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 280 °C
2: aq. NaOH / methanol
View Scheme
Multi-step reaction with 2 steps
1: 270 °C
2: KOH / methanol / Heating
View Scheme
((4-methoxy-2-(naphthalen-2-yloxy)phenyl)methylene)bis((3-methoxyphenyl)sulfane)
1221001-36-0

((4-methoxy-2-(naphthalen-2-yloxy)phenyl)methylene)bis((3-methoxyphenyl)sulfane)

A

9-methoxy-12-(3-methoxyphenylthio)-12H-benzo[a]xanthene
1221001-41-7

9-methoxy-12-(3-methoxyphenylthio)-12H-benzo[a]xanthene

B

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

Conditions
ConditionsYield
With scandium tris(trifluoromethanesulfonate) In dichloromethane at 20℃; Friedel Crafts reaction;
sodium 3-methoxyphenylsulfanesulfonate
1561023-51-5

sodium 3-methoxyphenylsulfanesulfonate

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

Conditions
ConditionsYield
With nickel(II) fluoride; triethoxyphenylsilane; palladium diacetate; trifluoroacetic acid In N,N-dimethyl acetamide at 100℃; Schlenk technique; Inert atmosphere;
C12H17NO2S

C12H17NO2S

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

Conditions
ConditionsYield
With sodium hydroxide In diphenylether at 80 - 120℃; for 8h; Flow reactor; Large scale;921.3 g
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

Bromoacetaldehyde diethyl acetal
2032-35-1

Bromoacetaldehyde diethyl acetal

1-[(2,2-diethoxyethyl)sulfanyl]-3-methoxybenzene
96803-85-9

1-[(2,2-diethoxyethyl)sulfanyl]-3-methoxybenzene

Conditions
ConditionsYield
Stage #1: 3-methoxybenzenethiol With potassium carbonate In acetonitrile at 20℃;
Stage #2: Bromoacetaldehyde diethyl acetal In acetonitrile for 15h;
100%
With potassium carbonate In acetone at 20℃; for 3h;100%
With potassium carbonate In acetone at 20℃; for 3h;100%
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

methyl iodide
74-88-4

methyl iodide

1-methoxy-3-methylsulfanyl-benzene
2388-74-1

1-methoxy-3-methylsulfanyl-benzene

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 0.5h;100%
With sodium hydride In N,N-dimethyl-formamide 1.) 0 deg C, 15 min, 2.) room temperature, 45 min;90%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In benzene for 48h; Substitution;
5-bromo-3-(2-bromo-4-fluorophenoxy)picolinonitrile
1065609-78-0

5-bromo-3-(2-bromo-4-fluorophenoxy)picolinonitrile

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

5-bromo-3-(2-bromo-4-fluorophenoxy)picolinonitrile

5-bromo-3-(2-bromo-4-fluorophenoxy)picolinonitrile

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.5h;100%
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

4,5-dibromothiophene-2-carboxaldehyde
38071-22-6

4,5-dibromothiophene-2-carboxaldehyde

4-bromo-5-[(3-methoxyphenyl)thio]thiophene-2-carbaldehyde
1138032-94-6

4-bromo-5-[(3-methoxyphenyl)thio]thiophene-2-carbaldehyde

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃;100%
With potassium carbonate In N,N-dimethyl-formamide at 20℃;
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

2-[(3-methoxyphenyl)sulfanyl]ethyl phenyl sulfone
1308834-07-2

2-[(3-methoxyphenyl)sulfanyl]ethyl phenyl sulfone

Conditions
ConditionsYield
With potassium carbonate In dichloromethane at 20℃; for 20h; Inert atmosphere;100%
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

acetic anhydride
108-24-7

acetic anhydride

S-3-methoxyphenyl ethanethioate

S-3-methoxyphenyl ethanethioate

Conditions
ConditionsYield
Stage #1: 3-methoxybenzenethiol; acetic anhydride With triethylamine In dichloromethane at 20℃; for 3h;
Stage #2: With hydrogenchloride In dichloromethane; water
100%
4-butanolide
96-48-0

4-butanolide

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

4-((3-methoxyphenyl)thio)butanoic acid sodium salt

4-((3-methoxyphenyl)thio)butanoic acid sodium salt

Conditions
ConditionsYield
With ethanol; sodium for 24h; Inert atmosphere; Reflux;100%
With sodium In ethanol for 24h; Inert atmosphere; Reflux;100%
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

(2R)-3-bromo-N-[4-cyano-3-(trifluoromethyl)phenyl]-2-hydroxy-2-methylpropanamide
206193-17-1

(2R)-3-bromo-N-[4-cyano-3-(trifluoromethyl)phenyl]-2-hydroxy-2-methylpropanamide

C19H17F3N2O3S

C19H17F3N2O3S

Conditions
ConditionsYield
Stage #1: 3-methoxybenzenethiol With sodium hydride In tetrahydrofuran; mineral oil
Stage #2: (2R)-3-bromo-N-[4-cyano-3-(trifluoromethyl)phenyl]-2-hydroxy-2-methylpropanamide In tetrahydrofuran; mineral oil at 20℃; for 20h;
100%
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

bis(3-methoxyphenyl)disulfide
59014-89-0

bis(3-methoxyphenyl)disulfide

Conditions
ConditionsYield
1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione In chloroform at 20℃; for 0.0166667h;99.6%
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione In chloroform at 20℃; for 1h; Inert atmosphere;97%
With titanium(IV) oxide; oxygen In acetonitrile under 750.075 Torr; for 0.416667h; Irradiation;96%
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

2-fluorobenzonitrile
394-47-8

2-fluorobenzonitrile

2-((3-methoxyphenyl)thio)benzonitrile

2-((3-methoxyphenyl)thio)benzonitrile

Conditions
ConditionsYield
With potassium fluoride on basic alumina; 18-crown-6 ether In acetonitrile for 18h; Heating;99%
With potassium fluoride on basic alumina; 18-crown-6 ether In acetonitrile for 18h; Heating;99%
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

methyl 2-(bromomethyl)-6-nitrobenzoate
61940-21-4

methyl 2-(bromomethyl)-6-nitrobenzoate

methyl 2-(3-methoxyphenylthiomethyl)-6-nitrobenzoate

methyl 2-(3-methoxyphenylthiomethyl)-6-nitrobenzoate

Conditions
ConditionsYield
With sodium bicarbonate; sodium chloride; triethylamine In dichloromethane99%
(1H-1,2,3-benzotriazol-1-yl)(2,3-dihydro-1H-indol-1-yl)methanethione
865075-55-4

(1H-1,2,3-benzotriazol-1-yl)(2,3-dihydro-1H-indol-1-yl)methanethione

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

2,3-dihydroindole-1-carbodithioic acid 3-methoxyphenyl ester

2,3-dihydroindole-1-carbodithioic acid 3-methoxyphenyl ester

Conditions
ConditionsYield
With sodium hydride In dichloromethane for 18h;99%
ethyl (2-chloroaceto)acetate
638-07-3

ethyl (2-chloroaceto)acetate

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

3-methoxybenzenethiol
16768-98-2

3-methoxybenzenethiol

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 0 - 20℃; for 2h;99%
With potassium hydroxide In methanol at 20℃; for 6h;
With potassium carbonate In DMF (N,N-dimethyl-formamide) at 20℃; for 2.16667h;
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

5-bromoacetyl-2,4-dimethylthiazole hydrobromide
76007-16-4

5-bromoacetyl-2,4-dimethylthiazole hydrobromide

1-(2,4-dimethylthiazol-5-yl)-2-(3-methoxyphenylsulfanyl) ethanone
374754-18-4

1-(2,4-dimethylthiazol-5-yl)-2-(3-methoxyphenylsulfanyl) ethanone

Conditions
ConditionsYield
With potassium hydroxide In ethanol; water99%
2-chloro-3-(phenylamino)naphthalene-1,4-dione
1090-16-0

2-chloro-3-(phenylamino)naphthalene-1,4-dione

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

2-(3-methoxyphenylthio)-3-(phenylamino)naphthalene-1,4-dione
1171120-72-1

2-(3-methoxyphenylthio)-3-(phenylamino)naphthalene-1,4-dione

Conditions
ConditionsYield
With triethylamine In methanol at 70℃; for 4h;99%
Stage #1: 3-methoxybenzenethiol With triethylamine In water for 0.0833333h; Green chemistry;
Stage #2: 2-chloro-3-(phenylamino)naphthalene-1,4-dione In water at 65℃; Green chemistry;
99%
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

4-bromo-8-nitroquinolin-2(1H)-one

4-bromo-8-nitroquinolin-2(1H)-one

4-(3-methoxyphenylthio)-8-nitroquinolin-2(1H)-one

4-(3-methoxyphenylthio)-8-nitroquinolin-2(1H)-one

Conditions
ConditionsYield
Stage #1: 3-methoxybenzenethiol With sodium hydride In N,N-dimethyl-formamide at 20℃; for 0.5h; Inert atmosphere;
Stage #2: 4-bromo-8-nitroquinolin-2(1H)-one In N,N-dimethyl-formamide at 20℃; for 2h; Inert atmosphere;
99%
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-butyl 3-methoxyphenyl sulfoxide
49833-47-8

tert-butyl 3-methoxyphenyl sulfoxide

Conditions
ConditionsYield
Stage #1: 3-methoxybenzenethiol; tert-butyl alcohol With perchloric acid; acetic anhydride; acetic acid at 20℃; for 24h; Cooling with ice;
Stage #2: With dihydrogen peroxide at 0 - 20℃; for 8h;
99%
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

Diphenylphosphine oxide
4559-70-0

Diphenylphosphine oxide

diphenylthiophosphinic acid-S-3-methoxyphenyl ester

diphenylthiophosphinic acid-S-3-methoxyphenyl ester

Conditions
ConditionsYield
With tert-Butyl peroxybenzoate; potassium iodide In dimethyl sulfoxide at 20℃; for 8h;99%
With oxygen; rose bengal In N,N-dimethyl-formamide at 20℃; for 12h; Schlenk technique; Inert atmosphere; Irradiation;91%
With sodium carbonate In N,N-dimethyl-formamide at 20℃; for 3h;77%
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

2,2,6-trimethyl-4-phenyl-1,4-diazabicyclo[4.1.0]heptan-5-one

2,2,6-trimethyl-4-phenyl-1,4-diazabicyclo[4.1.0]heptan-5-one

3-((3-methoxyphenylthio)methyl)-3,5,5-trimethyl-1-phenylpiperazin-2-one

3-((3-methoxyphenylthio)methyl)-3,5,5-trimethyl-1-phenylpiperazin-2-one

Conditions
ConditionsYield
With tris(pentafluorophenyl)borate In acetonitrile at 65℃; for 18h; Inert atmosphere;99%
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

benzenesufonyl hydrazide
80-17-1

benzenesufonyl hydrazide

S-(3-methoxyphenyl) benzenesulfonothioate

S-(3-methoxyphenyl) benzenesulfonothioate

Conditions
ConditionsYield
With tert.-butylhydroperoxide; sodium iodide In acetonitrile at 20℃; for 12h;99%
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

tert-butyl (2-oxo-1-propylindolin-3-ylidene)carbamate

tert-butyl (2-oxo-1-propylindolin-3-ylidene)carbamate

tert-butyl (3-((3-methoxyphenyl)thio)-2-oxo-1-propylindolin-3-yl)carbamate

tert-butyl (3-((3-methoxyphenyl)thio)-2-oxo-1-propylindolin-3-yl)carbamate

Conditions
ConditionsYield
With C12H15CoN2O6(1-)*K(1+) In dichloromethane at 20℃; for 0.0833333h; Schlenk technique; Green chemistry;99%
1-(4-(4-bromobenzoyl)piperidin-1-yl)ethanone
66309-71-5

1-(4-(4-bromobenzoyl)piperidin-1-yl)ethanone

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

1-(4-(4-((3-methoxyphenyl)thio)benzoyl)piperidin-1-yl)ethanone

1-(4-(4-((3-methoxyphenyl)thio)benzoyl)piperidin-1-yl)ethanone

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); potassium carbonate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In toluene at 120℃; for 24h; Sealed tube; Inert atmosphere;99%
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

2-fluoro-6-[(4-methylphenyl)sulfanyl]benzonitrile
175204-11-2

2-fluoro-6-[(4-methylphenyl)sulfanyl]benzonitrile

2-(3-Methoxy-phenylsulfanyl)-6-p-tolylsulfanyl-benzonitrile

2-(3-Methoxy-phenylsulfanyl)-6-p-tolylsulfanyl-benzonitrile

Conditions
ConditionsYield
With potassium fluoride on basic alumina; 18-crown-6 ether In acetonitrile for 18h; Heating;98%
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

2-fluoro-6-[(4-methylthio)phenoxy]benzonitrile

2-fluoro-6-[(4-methylthio)phenoxy]benzonitrile

2-(3-Methoxy-phenylsulfanyl)-6-(4-methylsulfanyl-phenoxy)-benzonitrile

2-(3-Methoxy-phenylsulfanyl)-6-(4-methylsulfanyl-phenoxy)-benzonitrile

Conditions
ConditionsYield
With potassium fluoride on basic alumina; 18-crown-6 ether In acetonitrile for 18h; Heating;98%
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

2,6 dichloropurine
5451-40-1

2,6 dichloropurine

2-chloro-6-[(3-methoxyphenyl)thio]purine

2-chloro-6-[(3-methoxyphenyl)thio]purine

Conditions
ConditionsYield
With potassium tert-butylate In isopropyl alcohol at 50℃;98%
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

5-(ethoxymethylene)-2,2-dimethyl-1,3-dioxane-4,6-dione
15568-86-2

5-(ethoxymethylene)-2,2-dimethyl-1,3-dioxane-4,6-dione

5-(3-methoxy-phenylsulfanylmethylene)-2,2-dimethyl-[1,3]dioxane-4,6-dione

5-(3-methoxy-phenylsulfanylmethylene)-2,2-dimethyl-[1,3]dioxane-4,6-dione

Conditions
ConditionsYield
With 1-butyl-3-methylimidazolium Tetrafluoroborate In ethyl acetate for 0.1h; microwave irradiation;98%
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

2-(4-fluorophenyl)-6-iodoimidazo[1,2-a]pyridine
478040-44-7

2-(4-fluorophenyl)-6-iodoimidazo[1,2-a]pyridine

2-(4-fluorophenyl)-6-(3-methoxyphenylsulfanyl)imidazo[1,2-a]pyridine

2-(4-fluorophenyl)-6-(3-methoxyphenylsulfanyl)imidazo[1,2-a]pyridine

Conditions
ConditionsYield
With copper(l) iodide; potassium carbonate; ethylene glycol In isopropyl alcohol at 80℃; for 20h;98%
2-bromo-pyridine
109-04-6

2-bromo-pyridine

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

2-[(3-methoxyphenyl)thio]pyridine

2-[(3-methoxyphenyl)thio]pyridine

Conditions
ConditionsYield
Stage #1: 2-bromo-pyridine With 1,2,3-Benzotriazole; copper(l) iodide In dimethyl sulfoxide for 0.166667h;
Stage #2: 3-methoxybenzenethiol With potassium tert-butylate In dimethyl sulfoxide at 100℃; Further stages.;
98%
With potassium carbonate In dimethyl sulfoxide at 110℃; for 18h; Inert atmosphere;82%
With copper(l) iodide; 1-Hydroxymethyl-1H-benzotriazole; potassium tert-butylate In dimethyl sulfoxide at 80℃;71%
With potassium carbonate In N,N-dimethyl-formamide at 110℃; for 20h;
With potassium carbonate In N,N-dimethyl-formamide at 110℃; for 20h;
ethyl 4,7-dichloro-6-fluoroquinoline-3-carboxylate

ethyl 4,7-dichloro-6-fluoroquinoline-3-carboxylate

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

C19H15NO3SClF

C19H15NO3SClF

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 25℃;98%
Stage #1: ethyl 4,7-dichloro-6-fluoroquinoline-3-carboxylate; 3-methoxybenzenethiol In N,N-dimethyl-formamide at 20℃; for 0.5h;
Stage #2: With potassium carbonate In N,N-dimethyl-formamide at 0 - 10℃; for 1h;
60%
tert-butyl {[5-bromo-4-(2-fluoropyridin-3-yl)-1,3-thiazol-2-yl]methyl}methylcarbamate
1138033-70-1

tert-butyl {[5-bromo-4-(2-fluoropyridin-3-yl)-1,3-thiazol-2-yl]methyl}methylcarbamate

3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

tert-butyl ({4-(2-fluoropyridin-3-yl)-5-[(3-methoxyphenyl)thio]-1,3-thiazol-2-yl}methyl)methylcarbamate
1138033-81-4

tert-butyl ({4-(2-fluoropyridin-3-yl)-5-[(3-methoxyphenyl)thio]-1,3-thiazol-2-yl}methyl)methylcarbamate

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In toluene at 105℃; for 12h;98%

15570-12-4Relevant articles and documents

Crampton

, p. 2112 (1971)

Copper-Catalyzed Direct Synthesis of Aryl Thiols from Aryl Iodides Using Sodium Sulfide Aided by Catalytic 1,2-Ethanedithiol

Xue, Hongyu,Jing, Bing,Liu, Shasha,Chae, Junghyun,Liu, Yajun

, p. 2272 - 2276 (2017/10/06)

A copper-catalyzed direct and effective synthesis of aryl thiols from aryl iodides using readily available Na 2 S·9H 2 O and 1,2-ethanedithiol was described. A variety of aryl thiols were readily obtained in yields of 76-99%. In this protocol, Na 2 S·9H 2 O was used as ultimate sulfur source, and 1,2-ethanedithiol functioned as an indispensable catalytic reagent.

Scandium triflate-catalyzed one-pot domino approach towards general and efficient syntheses of unsymmetrical 9-substituted xanthene derivatives

Singh, Ritesh,Panda, Gautam

scheme or table, p. 1097 - 1105 (2010/06/15)

A general and efficient one-pot cascade/tandem approach to synthesize unsymmetrical 9-aryl/heteroaryl xanthenes has been developed under extremely mild reaction conditions using 10 mol% Sc(OTf)3 as a catalyst. This strategy has been further extended to synthesize 9-(thioaryl) xanthenes through tandem carbon-sulfur (C-S) and carbon-carbon (C-C) bond formation. Novel C-C and C-S bond cleavage promoted by Sc(OTf)3 is also discussed during mechanistic investigation. The Royal Society of Chemistry.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 15570-12-4