15576-83-7

Upstream product

• 1631-82-9 chloro(methyl)phenylsilane 
• 71-36-3 butan-1-ol 
• 130648-88-3 [2-(4,5-dihydrofuryl)]methylphenylsilane 
• 3027-21-2 dimethoxy(methyl)phenylsilane 
• 5593-70-4 titanium (IV) butoxide 
• 77-63-4 2,4,6,8-tetraphenyl-2,4,6,8-tetramethylcyclotetrasiloxane 

Relevant academic research and scientific papers

PRODUCTION METHOD FOR ALKOXYSILANES

Provided is a method for efficiently producing alkoxysilanes that are useful as various functional chemicals. In order to produce alkoxysilanes efficiently, an ethoxy- or methoxysilane and an alcohol are caused to react using, as a catalyst, for instance an inorganic solid acid having a regular-pore and/or layered structure. Zeolites, montmorillonites or the like can be used as the inorganic solid acid. When a zeolite is used as the catalyst, the silica/alumina ratio of the zeolite ranges preferably from 5 to 1000. The reaction can be promoted through irradiation of microwaves.

Alkoxysilane, [...] acids and its manufacturing method (by machine translation)

PROBLEM TO BE SOLVED: alkylalkoxysilane compounds useful as a chemical product having various functions, and [...] or obtained from the same and to provide a manufacturing method thereof. SOLUTION: the alkylalkoxysilane, or a methoxy group and an ethoxy group, an alkyl group oxystyrene, thioalkyl group, on the same silicon atom or an alkyl group halogenopyridine structure having, for example, a plurality of silane-based or methoxysalicylic naphtholsulfonic, regular porous structure having a solid acid and alcohol in the presence of catalyst inorg. by reaction can be produced. Furthermore, water and the like of [...] alkylalkoxysilane obtained by reaction, is allowed to coexist with acid or the like can be performed efficiently. Selected drawing: fig. 1 (by machine translation)

Reactions of dihydrofurylsilanes with O- and N-nucleophiles

It was shown that the reaction of 4,5-dilydro-2-furylsilanes with alcohols and lithium N,N-diethylamide leads to substitution of the dihydrofuryl group by the nucleophilic residue. 1997 Plenum Publishing Corporation.

Separation of chiral silicon compounds using permethylated α-, β-, and γ-cyclodextrin capillary GC columns

Permethylated α-, β-, and γ-cyclodextrin GC stationary phases were used to resolve racemic silane derivatives, R1R2Si*PhMe. Particularly good resolutions were obtained on the β-CD phase for racemates containing a silanol g