1558003-69-2Relevant academic research and scientific papers
Asymmetric total synthesis of (+)-inthomycin C via O-directed free radical alkyne hydrostannation with Ph3SnH and catalytic Et3B: Reinstatement of the zeeck-taylor (3 R)-Structure for (+)-Inthomycin C
Hale, Karl J.,Grabski, Milosz,Manaviazar, Soraya,Maczka, Maciej
supporting information, p. 1164 - 1167 (2014/03/21)
A new pathway to (+)-inthomycin C is reported that exploits an O-directed free radical hydrostannation reaction on (-)-12 and a Stille cross-coupling as key steps. Significantly, the latter process was effected on 19 where a gauche-pentane repulsive inter
