155830-69-6 Usage
Reaction
Ligand for Palladium-catalyzed amination of aryl halides
Ligand for Rhodium-catalyzed asymmetric alcoholysis and aminolysis of oxabenzonorbornadiene
Ligand for Rhodium-catalyzed asymmetric ring opening of oxabicyclic alkenes with organoboronic acids
Ligand for Copper-catalyzed asymmetric 1,4-hydrosilylations of α,β-unsaturated esters
Ligand for Ruthenium-catalyzed asymmetric hydrogenation of N-sulfonated-α-dehydroamino acids
Ligand for Rhodium-catalyzed asymmetric hydrogenation of enamines
Ligand for Palladium-catalyzed Kumada coupling of aryl and vinyl tosylates
Ligand for Palladium-catalyzed enantioselective synthesis of aryl sulfoxides
Ligand for Rhodium-catalyzed enantioselective insertion of a carbenoid carbon into a C-C bond
Chemical Properties
Orange powder
Uses
It may be used as a ligand in the palladium-catalyzed alkoxycarbonylation of 6-bromo-1,4-benzodioxane with sodium tert-butoxide to form the corresponding tert-butyl ester.
General Description
(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (PPF-tBu) is a chiral ferrocenyl diphosphine ligand.
Check Digit Verification of cas no
The CAS Registry Mumber 155830-69-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,5,5,8,3 and 0 respectively; the second part has 2 digits, 6 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 155830-69:
(8*1)+(7*5)+(6*5)+(5*8)+(4*3)+(3*0)+(2*6)+(1*9)=146
146 % 10 = 6
So 155830-69-6 is a valid CAS Registry Number.
InChI:InChI=1/C27H35P2.C5H5.Fe/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h8-21H,1-7H3;1-5H;/t21-;;/m1../s1
