155854-57-2Relevant academic research and scientific papers
Stepwise building of polyphosphirene chains
Tran Huy, Ngoc H.,Ricard, Louis,Mathey, Francois
, p. 1253 - 1255 (2001)
No end in sight: the mono-, bi-, and triphosphirenes 2, 3, and 5, respectively, are prepared by a simple iterative method (see scheme; 1 = [Ph ≡ CPW(CO)5], 4 = [PhPW(CO)5]); these oligomers offer numerous possibilities in coordination chemistry and catalysis. They can serve to create numerous other classes of polyphosphine chains by ring opening or ring expansion of the phosphirene units.
The equilibrium between 1H- and 2H- phospholes : influence of the substitution pattern and scope
Laporte, F.,Mercier, F.,Ricard, L.,Mathey, F.
, p. 843 - 850 (2007/10/02)
The equilibria between 1H- and 2H- phospholes have been studied using diphenylacetylene as a selective trapping reagent of the 2H-species. 1-Phenylphosphole equilibrates with 5-phenyl-2H-phosphole at 150 deg C.This 2H-phosphole reacts with tolane to give
