1558811-69-0Relevant articles and documents
Tertiary thiols from allylic thiocarbamates by tandem enantioselective [3,3]-sigmatropic rearrangement and stereospecific arylation
Mingat, Gaelle,Maclellan, Paul,Laars, Marju,Clayden, Jonathan
, p. 1252 - 1255 (2014/03/21)
The synthesis of tertiary thiols in enantiomerically enriched form is accomplished by lithiation of enantiomerically enriched N-aryl allylic thiocarbamates. Formation of an allyllithium derivative promotes intramolecular N to C aryl migration to the posit