155947-76-5Relevant academic research and scientific papers
Synthesis and Molecular Structure of Tris(η4-2,4-di-tert-butyl-1,3-diphosphacyclobutadiene)molybdenum(0)
Cloke, F. Geoffrey N.,Flower, Kevin R.,Hitchcock, Peter B.,Nixon, John F.
, p. 489 - 490 (1994)
Cocondensation of molybdenum vapour with the phosphaalkyne t-BuCP affords the title compound, whose molecular structure has been determined by single crystal X-ray diffraction.
Ambiphilicity: A characteristic reactivity principle of π-bound phosphorus heterocycles
Topf, Christian,Clark, Timothy,Heinemann, Frank W.,Hennemann, Matthias,Kummer, Susanne,Pritzkow, Hans,Zenneck, Ulrich
, p. 4047 - 4052 (2007/10/03)
Bicycles made in crystals: The phosphorus atoms of the: π ligand 1,3-diphosphete turn out to be ambiphilic centers with pronounced intramolecular reactivity. This property results in a temperature-dependent bond formation in [(2,4-di-tBu-1,3-diphosphete)
