156088-10-7

Basic information

• Product Name: 3-phenyl-5-(tert-butyldimethylsilyl)methylisoxazole
• CAS NO: 156088-10-7
• Molecular Weight: 273.45
• Mol File: 156088-10-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-phenyl-5-(tert-butyldimethylsilyl)methylisoxazole(CAS DataBase Reference)
• NIST Chemistry Reference: 3-phenyl-5-(tert-butyldimethylsilyl)methylisoxazole(156088-10-7)
• EPA Substance Registry System: 3-phenyl-5-(tert-butyldimethylsilyl)methylisoxazole(156088-10-7)

Safety Data

• Hazardous Substances Data: 156088-10-7(Hazardous Substances Data)

Upstream product

• 1008-74-8 5-methyl-3-phenylisoxazole 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 94225-41-9 (Z)-5-<2-(tert-butyldimethylsilyl)amino-2-phenylvinyl>-3-phenylisoxazole 

Relevant articles and documents

RING-TRANSFORMATION EQUILIBRIUM WITH PARTICIPATION OF ?-BONDED S(IV) IN AN ISOTHIAZOLE SYSTEM. SYNTHESIS OF NON-RING-TRANSFORMED 5-(2-AMINOVINYL)ISOTHIAZOLE DERIVATIVE VIA 1,3-SILYL GROUP SHIFT

Substituents at 5-position of 5-amino-3-methyl- and 3-p-chlorophenyl-5-methylisothiazoles (7 and 8) were silylated and then lithiated to couple with aromatic nitriles in order to afford the adducts (4 and 5) via 1,3-silyl group shift.Desilylation of 5 wit