156091-20-2

Basic information

• Product Name: C₉H₉Cl₂F₃Se
• Synonyms: C₉H₉Cl₂F₃Se
• CAS NO: 156091-20-2
• Molecular Weight: 324.032
• Mol File: 156091-20-2.mol

Chemical Properties

• CAS DataBase Reference: C₉H₉Cl₂F₃Se(CAS DataBase Reference)
• NIST Chemistry Reference: C₉H₉Cl₂F₃Se(156091-20-2)
• EPA Substance Registry System: C₉H₉Cl₂F₃Se(156091-20-2)

Safety Data

• Hazardous Substances Data: 156091-20-2(Hazardous Substances Data)

Upstream product

• 156091-18-8 1-Methyl-4-(2,2,2-trifluoro-ethylselanyl)-benzene 
• 21856-94-0 di-p-tolyl diselenide 

Downstream Products

• 156091-24-6 C₉H₉F₃OSe 

Relevant articles and documents

2,2,2-Trifluoroethyl aryl selenides: ArSeCH2CF3 (Ar = C6H5, p-CH3C6H4) and their derivatives ArSe(O)CH2CF3 and ArSe(X)2CH2CF3 (X = Cl, Br, OOCCF3)

The title selenides were prepared in good yield by reacting the appropriate aryl selenolate anions with 2,2,2-trifluoroethyltosylate in refluxing tetrahydrofuran.These unsymmetrical bivalent selenides can be oxidised to the corresponding compounds of tetravalent selenium, ArSe(X)2CH2CF3 (X=Cl and Br) with elemental chlorine and bromine.The latter, upon basic hydrolysis, gave the selenoxides, ArSe(O)CH2CF3.Selenoxides have also been formed by direct reaction of the selenides with hydrogen peroxide.Upon reaction with trifluoroacetic anhydride, these gave trifluoroacetate derivatives, ArSe(OOCCF3)2CH2CF3, in quantitative yield.The compounds have been characterized via elemental analysis, infrared spectra, 1H and 19F NMR spectra, and mass spectra.